21:00 – lørdag 19 oktober, 2019
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| Atletico Madrid | 1-1 | Valencia |
Fuldtid
 | ||
| 90' |  | Lee Kangin |
| 82' |  | 1-1 Dani Parejo |
| 77' |  | Lee Kangin Denis Cheryshev |
| 71' | | Carlos Soler Ferrán Torres |
Marcos Llorente Álvaro Morata | | 68' |
| 65' | | Kevin Gameiro Geoffrey Kondogbia |
Renan Lodi Mario Hermoso | | 54' |
Thomas Lemar Thomas Partey | | 54' |
| Pause 1-0 | ||
| Joao Félix |  | 44' |
| 39' | | Denis Cheryshev |
1-0 Diego Costa Straffespark |  | 36' |
| Thomas Partey | | 29' |
| ||