18:30 – lørdag 5 oktober, 2019
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La Liga
| Valencia | 2-1 | Cd Alaves |
Fuldtid
 | ||
Rubén Sobrino Denis Cheryshev |  | 90' |
| 89' |  | 2-1 Lucas Perez |
| 84' | | Borja Sainz Rodrigo Ely |
2-0 Dani Parejo Straffespark |  | 83' |
| 82' |  | Antonio Sivera |
| 73' | | Aleix Vidal Ximo Navarro |
Mouctar Diakhaby Ferrán Torres | | 70' |
Manuel Vallejo Rodrigo | | 59' |
| Pause 1-0 | ||
| 1-0 Maximiliano Gómez | | 27' |
| 21' | | Pere Pons Tomás Pina |
| 15' | | Manu García |
| 15' | | Rubén Duarte |
| Daniel Wass | | 14' |
| ||