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18:55 – torsdag 29 oktober
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Qarabag FK
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3
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Villarreal
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- Dplay
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| 90' |  | 1-3 Paco Alcácer Straffespark |
| Abbas Hüseynov |  | 90' |
| 90' |  | Rogelio Funes Mori Juan Foyth |
Tural Bayramov Owusu Kwabena | | 90' |
İsmayıl İbrahimli Patrick | | 90' |
| 86' | | Alejandro Rodríguez Samuel Chukwueze |
| 84' |  | 1-2 Paco Alcácer |
Elvin Dzhafarquliyev Abdellah Zoubir | | 82' |
| 80' | | 1-1 Yeremi Santos |
| 1-0 Owusu Kwabena | | 78' |
| 74' | | Paco Alcácer Takefusa Kubo |
| 74' | | Yeremi Santos Carlos Bacca |
| 74' | | Moi Gómez Jaume Costa |
Mahir Mədətov Filip Ozobić | | 61' |
Uroš Matič Jaime Romero | | 61' |
| Pause 0-0 | ||
| Patrick | | 39' |
| 25' | | Vicente Iborra |
| Filip Ozobić | | 13' |
| Jaime Romero | | 2' |
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